Imikhiqizo
2-FluoroMobiphenyl; Case No.: 321-60-8
Amanyanjana: 2-Fluorobiphenyl; 321-60-8; 2-Fluoro-1,1-BIPHENYL; 2-Fluoro-; 2-Fluoro-Biphenyl; C12h9f; CCRIS 1659; EINECS 206-290-7; NSC 10366; kc8q87v4qy; dtxsid5047744; mfcd00000317; NSC-10366; 2-Fluoro- (2 ', 5', 6 '-2HH5) -1,1'-BIPHEnY; 64420-95-7; O-Fluorobiphenl; 2-Fluoro-; 2-Fluorobiphenyl, I-96%; Unii-KC8Q87V4qy; Stycks201614; Chemblid122521; DTXCID50277728; kleckhe.cofffaxcxjybc-uhfffaysa-; AMY21_2029; I-AMY21_2029 12; AC8710; Akos006222514; CS-W017594; NCGC00594; NCGC00260458-01; I-PS-11571; I-SY032390; I-purum,> = 98.0% (GC); F0265; FT-0612430; 10.14272 / klecyolobipfqxc-uhfffaysa-n; Cyclohexane; A821178; doi: 10.14272 / kleckheoqffqxjybc-uhfffaysa-n; w-106853; Q63409297
Impahla yamakhemikhali ye-2-fluorobiphenyl
● Ukubukeka / umbala: off-white crystalline powder
● Ingcindezi ye-Vapor: 1.11E-08Mmhg ngo-25 ° C
● Iphuzu elincibilikayo: 71-74 ° C (Lit.)
● Inkomba evulekayo: 1.607
● Iphuzu elibilayo: 248 ° C ku-760 mmhg
● Iphuzu le-Flash: 94.4 ° C
● Psa:0.00000
● Hlensity: 1.083 g / cm3
● Logp: 3.49270
● Isitoreji Temp.:Store ngezansi + 30 ° C.
● I-allubility yamanzi .:Shuble ngotshwala, ether. Insoluble emanzini.
● xLogp3: 4
● I-Hydrogen Bond Donor Count: 0
● Ukubalwa Kwama-Hydrogen Bond kwamukelwa: 1
● I-rotatable bond count: 1
● Isisindo esiqondile: 172.068828449
● Isibalo se-athomu esindayo: 13
● Ukuba yinkimbinkimbi: 149
● Ilebuli ye-TATST DOT: Class 9
Imininingwane Ephelile
● pictograph (s):
Xn,
T,
I-XI
● Amakhodi Anobungozi: XI, T, XN, N
● Izitatimende: 36/37/38-63-43-23 / 24/40-45-40-50/50-50/50-50 / 53-41-37
● Izitatimende Zokuphepha: 22-24/15-36 / 37/36-36 / 37-23-53-61-60-39-26
-Sizayo
Amakilasi Amakhemikhali:Amanye amakilasi -> Halogenited polyraromatics
Ukumamatheka kwe-canonical:C1 = CC = C (C = C1) C2 = CC = CC = C2F
Sebenzisa:I-2-FluoRoBorobiphenyl isetshenziswa njengemithi, izidakamizwa zezilwane kanye nokuhlanganiswa kwe-organic okuphakathi. I-2-FluoroMobiphenyl yasetshenziswa njengezinga langaphakathi lokuhlaziywa kokungcoliswa kwemvelo ekusondelweni kwe-sediments kanye negesi i-chromatography-mass spectrometry, njenge-carbon & nenergy yodwa ye-P. Pseudoalcaligenes.
Isingeniso Esinemininingwane
2-Fluorobiphenyl, eyaziwa nangokuthi i-Ortho-Fluorobiphenyl, iyindawo yamakhemikhali equkethe i-biphenyl molecule ene-athomu le-fluorine elinamathiselwe kwelinye lamasongo we-phenyl. Ifomula yayo yamakhemikhali yi-C12h9f.
I-2-FluoroMobiphenyl iyi-colorless to pale ketshezi ophuzi ophuzi ngesisindo samangqamuzana acishe abe ngu-178.20 g / mol. Inobubanzi bokuncibilika kwe-68-70 ° C nephuzu elibilayo lika-272 ° C. I-Compound inobude be-1.15 g / cm³.
Ukuhlanganiswa kwe-2-fluorobiphenyl kungatholakala ngezindlela ezahlukahlukene, kufaka phakathi ukusabela kwe-fluorobelene ne-Phenyl Lithium noma i-Phenyl reagents reagents. Kungabuye kwahlaziswe nge-Palladium-Catalyzed Cross-Cross-couptions esheshayo phakathi kwe-fluorobelene ne-phenyylobor acid.
Ngokwezicelo, 2-Fluorobiphenyl kuvame ukuqashwa njengento yokuqala noma indawo yokwakha e-organic synthesis. Kusetshenziswa ekukhiqizweni kwemithi, ama-agrochemicals kanye namakhemikhali akhethekile. Ukufakwa kwama-athomu we-fluorine ezihlanganisweni ze-organic kungathonya kakhulu ukuvumelanisa kanye nezakhiwo.
Ngaphezu kwalokho, i-Compound ithola izinhlelo zokusebenza kumakhemikhali wezokwelapha, lapho ukwethulwa kwama-fluorine kungaqhakambisa khona i-potency, ukukhethwa, nokuqina kwe-metabolic kwama-molecule wezidakamizwa. Kusetshenziswa futhi ku-Material Science, ngokuqondile ku-synther yama-polymers ahlanganisiwe ngokuqina okuthuthukile okuthuthukile, ukumelana kwamakhemikhali, namandla aphansi. Lawa ma-polymers asetshenziselwa ukugqoka, amafilimu, ama-membranes, nakwezinye izinto ezikhethekile.
Njenganoma ikuphi amakhemikhali, kufanele kuthathwe ukuqapha lapho uphatha ama-2-fluorobiphenyl. Kufanele isetshenziswe endaweni enomoya owanele, kanye namagiya avikelayo afanele, kufaka phakathi amagilavu, ama-goggles kanye namajazi welebhu, kufanele agqokwe. Izindlela ezifanele zokugcina nokulahla kufanele zilandelwe ngokuya ngemithetho yezokuphepha.
Isicelo
I-2-fluorobiphenyl inokusetshenziswa okuningi okungaba khona kanye nezinhlelo zokusebenza. Nazi izibonelo ezimbalwa:
Synthesis yamakhemikhali:I-2-fluoroMobiphenyl ingasebenza njengento yokuqala noma i-board block ekuhlanganiseni kwamakhompiyutha ahlukahlukene ezi-organic. Kungavumela ukwethulwa kwe-athomu ye-fluorine ku-molecule eyinkimbinkimbi, engadlulisela izakhiwo ezifiselekayo njengokuqina kwamakhemikhali noma umsebenzi wemvelo oguquliwe.
Izemithi:Ukuguqulwa kwesakhiwo kwama-molecule e-organic ngama-athomu ama-fluorine, abizwa ngokuthi ama-fluorine, athole ukunakwa embonini yezemithi. Amakhompiyutha afakwe ama-fluolinated avame ukukhombisa izakhiwo ezithuthukile zezidakamizwa, njengokuqina kwe-metabolic okuthuthukile, ukukhuphuka kwe-lipophilicity, kanye ne-bioavailability ethuthukisiwe. Ngakho-ke, i-2-fluorobiphenyl ingahle isetshenziswe njenge-ejenti evuthayo ekubumbeni kwemithi efihliwe.
Isayensi Yezinto Zokusebenza:Amakhompiyutha ahlanganisiwe asetshenziswayo asetshenziswa ekwakhiweni kwezinto ezithuthukisiwe ezinezakhiwo ezihlukile. Isibonelo, i-2-Fluorobiphenyl ingafakwa kuma-polymers, ama-resins, kanye nokumboza ukuthuthukisa ukuqina kwabo okushisayo, ukumelana kwamakhemikhali, kanye nezinto zikagesi.
Ucwaningo Nentuthuko: I-2-fluoroMobiphenyl ingasetshenziswa njengengxenye yesethenjwa noma ejwayelekile kumasu wokuhlaziya, njenge-chromatography yegesi, ukukhomba kanye nokunciphisa amakhompiyutha ajwayelekile kumasampula ahlukahlukene. Ingasetshenziswa futhi njenge-compound emodeli yokutadisha ukuphendula kwamakhemikhali noma ukuphenya ngokuziphatha kwamakhompiyutha anamanzi ezindaweni ezihlukile.
Lezi izibonelo ezimbalwa nje zokusetshenziswa okungenzeka kwe-2-fluorobiphenyl. Kubalulekile ukuqaphela ukuthi izinhlelo ezithile ezingadinga ukuguqulwa okwengeziwe noma ukuhlanganiswa namanye amakhompiyutha ukufeza izakhiwo ozifunayo noma ukusebenza.
